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Study on enzymatic hydrolysis of steam exploded straw by using shaking ball

SUN Zhanwei, FU Xiaoguo, CHEN Hongzhang, WANG Yanhui, MA Runyu

《化学科学与工程前沿（英文）》 2008年 第2卷 第1期   页码 22-27 doi: 10.1007/s11705-008-0002-7

摘要： A novel method of enzymatic hydrolysis was developed in this paper to produce a high conversion yield and hydrolysis rate. A comparison was described by using three methods of enzymatic hydrolysis and adsorption of steam exploded straw (SEWS): shaking ball in the regime, shaking with stirrer bed, and static state. The most adequate filter-paper activity, speed and reaction time were 3.6 × 10 mol/(smL), 150 r/min and 24 h, respectively, with the reducing sugar yield of 0.43. The results showed that the method of shaking ball produced the highest adsorption, conversion yields and hydrolysis rate of the enzyme. This might be due to the continuous frequency increase of enzyme adsorption and desorption on the substrate surface as well as the relieved end-product inhibition. The morphological variation of SEWS was characterized by environmental scanning electron microscopy (ESEM).

关键词： adequate filter-paper     comparison     conversion     continuous frequency     substrate    

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The energy-free purification of trace thallium(I)-contaminated potable water using a high-selective filterpaper with multi-layered Prussian blue decoration

《化学科学与工程前沿（英文）》 doi: 10.1007/s11705-023-2379-8

摘要： Thallium is a highly toxic metal, and trace amount of thallium(I) (Tl+) in potable water could cause a severe water crisis, which arouses the exploitation of highly-effective technology for purification of Tl+ contaminated water. This report proposes the multi-layered Prussian blue (PB)-decorated composite membranes (PBx@PDA/PEI-FP) based on the aminated filter papers for Tl+ uptake. Extensively characterization by Fourier transform infrared spectrometer-attenuated total reflectance, scanning electron microscope, thermogravimetric analysis, X-ray photoelectron spectroscopy and X-ray diffraction were performed to confirm the in situ growth of cubic PB crystals on filter paper membrane surfaces via the aminated layers, and the successful fabrication of multi-layered PB overcoats via the increasing of aminated layers. The effect of PB layers on Tl+ removal by PBx@PDA/PEI-FP from simulated drinking water was evaluated as well as the influence of different experimental conditions. A trade-off between PB decoration layer number and PB distribution sizes is existed in Tl+ uptake by PBx@PDA/PEI-FP. The double-layered PB2@PDA/PEI-FP membrane showed the maximum sorption capacity, but its Tl+ uptake performance was weakened by the acid, coexisting ions (K+ and Na+) and powerful operation pressure, during filtrating a large volume of low-concentrated Tl+-containing water. However, the negative effect of coexisting ions on the Tl+ uptake could be effectively eliminated in weak alkaline water, and the Tl+ removal was increased up to 100% without any pressure driving for PB2@PDA/PEI-FP membrane. Most importantly, PB2@PDA/PEI-FP displayed the high-efficiency and high-selectivity in purifying the Tl+-spiked Pearl River water, in which the residual Tl+ in filtrate was less than 2 μg·L–1 to meet the drinking water standard of United States Environmental Protection Agency. This work provides a feasible avenue to safeguard the drinking water in remote and underdeveloped area via the energy-free operation.

关键词： membrane adsorption     Prussian blue     energy-free filtration     potable water     trace thallium(I)    

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结合基于滤纸的DNA提取技术和RPA-LFD检测技术对有毒植物钩吻进行快速鉴别

郑夏生, 安文丽, 姚晖, 徐江, 陈士林

《工程（英文）》 2021年 第7卷 第1期   页码 14-16 doi: 10.1016/j.eng.2020.02.012

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Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1010-1027 doi: 10.1007/s11705-023-2307-y

摘要： Powering the future, while maintaining strong socioeconomic growth and a cleaner environment, is going to be one of the biggest challenges faced by mankind nowadays. Thus, there is a transition from the use of fossil fuels to renewable energy sources. Cellulose, the main component of paper, represents a unique type of bio-based building blocks featuring exciting properties: low-cost, hierarchical fibrous structures, hydrophilicity, biocompatible, mechanical flexibility, and renewability, which make it perfect for use in paper-based sustainable energy storage devices. This review focuses on lithium-ion battery application of celluloses with cellulose at different scales, i.e., cellulose microfibers, and nanocellulose, and highlights the new trends in the field. Recent advances and approaches to construct high mass loading paper electrodes toward high energy density batteries are evaluated and the limitations of paper-based cathodes are discussed. This will stimulate the use of natural resources and thereby the development of renewable electric energy systems based on sustainable technologies with low environmental impacts and carbon footprints.

关键词： cellulose     paper electrodes     Li-ion batteries     high energy density    

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Research progress on low dielectric constant modification of cellulose insulating paper for power transformers

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 991-1009 doi: 10.1007/s11705-022-2259-7

摘要： Because of the increase in the transmission voltage levels, the demand for insulation reliability of power transformers has increasingly become critical. Cellulose insulating paper is the main insulating component of power transformers. To improve the insulation level of ultrahigh voltage transformers and reduce their weight and size, reducing the dielectric constant of oil-immersed cellulose insulating paper is highly desired. Cellulose is used to produce power-transformer insulating papers owing to its excellent electrical properties, renewability, biodegradability and abundance. The dielectric constant of a cellulose insulating paper can be effectively reduced by chemical or physical modification. This study presents an overview of the foreign and domestic research status of the use of modification technology to reduce the dielectric constant of cellulose insulating papers. All the mentioned methods are analyzed in this study. Finally, some recommendations for future modified cellulose insulating paper research and applications are proposed. This paper can provide a reference for further research on low dielectric constant cellulose insulating paper in the future.

关键词： low dielectric constant     chemical and physical modification     cellulose insulating paper     transformer     nanomaterials.    

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Technical measures to achieve a cleaner production mode for recycled paper mills

Chao HE, Zhaolin GU, Shucheng YANG, Jidong LIANG, Weina DAI, Yanling HE

《环境科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 466-474 doi: 10.1007/s11783-010-0242-x

摘要： China’s paper production reached 79.8 ×10 t in 2008 and ranked number one in the world. Because of its high consumption of water, energy and materials and its serious pollution, the present processes are not likely to be sustainable. An alternative, the closed Water Loop-Papermaking Integration (WLPI) method, is put forward in this paper. The WLPI method can be realized in a recycled paper mill by adding technologies and using recycled water. Many industrial case studies have shown that a large quantity of water, energy and materials can be saved, and the quantity of waste sludge and wastewater discharge was minimized by using the WLPI method. The design of the water reuse system, control of calcium hardness, water recycling and minimal waste sludge are discussed. Anaerobic technology plays an important role in the WLPI method to lower cost, energy use and waste. In the brown paper and coated white board production, zero-effluent discharge can be realized. Fresh water consumption is only 1–2 m ·t . For the paper mills with deinking and bleaching processes, about 10 m ·t of fresh water and a similar amount of effluent discharge are needed. Power saving using anaerobic technology is 70% when recycled water is used in comparison with the conventional activated sludge process. Waste sludge can be decreased to about 5% of the initial process due to reuse of the waste sludge and the lower bio-sludge production of the anaerobic process.

关键词： water reuse     zero discharge     anaerobic treatment     recycled paper     cleaner production    

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Investigation of electrochemical degradation and application of e-paper dyes in organic solvents

Luhai LI, Ming WANG, Yi FANG, Shunan QIAO

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 182-185 doi: 10.1007/s11705-009-0062-3

摘要： To avoid environmental pollution due to organic dye solutions, the electrophoresis and degradation of dye in organic solvents such as alcohol were investigated. Many dyes were tested in the Indium tin oxide (ITO) electrode driving cell, and about 15 dyes moved under voltage driving. Both the curves of ultraviolet-visible (UV-Vis) and infrared (IR) spectra of the electrophoresis samples showed that the metal complexes Red 04 and Acid Black 1 were degradable in alcohol solution by electrochemical reaction. The cyclic volt-ampere curves of the samples from the electrochemical working station proved that electrochemical reactions took place. Based on the analysis of UV-Vis and IR spectra, the electrochemical degradation products of azo and metal complex azo dyes at lower voltage driving (1-5 V) in organic solvents are oxidized azobenzene, not hydrazine, which was found in the electrochemical degradation of dye water solutions. When the ITO electrode is modified by a polyimide (PI) film to a thickness less than 4 μm, the electrochemical degradation of the dye in alcohol solution will not appear in the cyclic volt-ampere curves. A dye electrophoresis in organic solution flexible prototype e-paper display was formed and the display picture is shown.

关键词： electrochemical degradation     electrophoresis     e-paper     oxidized azobenzene group    

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Easily-manufactured paper-based materials with high porosity for adsorption/separation applications in

《化学科学与工程前沿（英文）》 2023年 第17卷 第7期   页码 830-839 doi: 10.1007/s11705-022-2267-7

摘要： A multi-functional porous paper-based material was prepared from grass pulp by simple pore-forming and green cross-linking method. As a pore-forming agent, calcium citrate increased the porosity of the paper-based material from 30% to 69% while retaining the mechanical strength. The covalent cross-linking of citric acid between cellulose fibers improved both the wet strength and adsorption capacity. In addition, owing to the introduction of high-content carboxyl groups as well as the construction of hierarchical micro-nano structure, the underwater oil contact angle was up to 165°. The separation efficiency of the emulsified oil was 99.3%, and the water flux was up to 2020 L·m–2·h–1. The theoretical maximum adsorption capacities of cadmium ion, lead ion and methylene blue reached 136, 229 and 128.9 mg·g–1, respectively. The continuous purification of complex wastewater can be achieved by using paper-based materials combined with filtration technology. This work provides a simple, low cost and environmental approach for the treatment of complex wastewater containing insoluble oil, organic dyes, and heavy metal ions.

关键词： adsorption     oil–water separation     underwater superoleophobicity     wastewater treatment    

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论文演化图：学术文献多视角结构化检索 None

Dan-ping LIAO, Yun-tao QIAN

《信息与电子工程前沿（英文）》 2019年 第20卷 第2期   页码 187-205 doi: 10.1631/FITEE.1700105

摘要： 学术文献检索关注于选取最可能符合用户信息需求的论文。目前大部分检索系统局限于输出相关文献列表，而这些检出文献相互独立。本文旨在揭示检索结果的相互关系。提出一种为学术文献建立结构化检索结果的方法，称为论文演化图（PEG）。PEG采用多个演化链描述查询输入信息在不同主题方向的演化情况。通过论文作者、参考文献引用、论文内容信息这3个视角，PEG能够发现文献之间各种潜在关系，并多视角展示文献演化过程。该文献检索系统支持关键词、单篇论文、双论文3种查询方式。PEG构造主要有3个步骤：首先，采用元图分解法把文献软聚合为多个群落，获取每篇论文的主题分布；其次，从与查询相关的文献群落中提取主题连贯性演化链。每条演化链反映查询信息的某一视角；最后，提取的演化链组合形成论文演化图，可以覆盖查询涉及的所有主题。基于真实文献数据库的实验结果表明，该方法能够建立对用户有意义的论文演化图。

关键词： 论文演化图；学术文献检索；元图分解；主题连贯性    

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现代造纸机的节能与降耗

陈克复,杨旭

《中国工程科学》 2012年 第14卷 第7期   页码 4-8

摘要：

讨论了装备控制先进、车速在准高速以上的现代造纸机实现节能降耗的几个途径，即改进各操作单元的结构、实施先进的关键技术与装备及提高其抄造率和产品成品率来提高整机效率。详细介绍了现代造纸机各操作单元的先进关键技术，以及这些关键技术对节能降耗的作用。通过分析现代造纸机在技术上仍存在的科技难题及我国的实际情况，提出研发国产现代造纸机的车速及幅宽的定位，并对我国研发及生产现代造纸机装备方面提出了合理的建议。

关键词： 节能降耗     现代造纸机     关键技术    

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Error compensation for tool-tip trace during cutting of laminated paper for rapid prototyping

Yucheng DING, Changhe LI, Dichen LI, Guoxin YU

《机械工程前沿（英文）》 2009年 第4卷 第2期   页码 111-119 doi: 10.1007/s11465-009-0020-2

摘要： Laminated object manufacturing (LOM) is one of the commercialized rapid prototyping (RP) processes, where a focused laser is usually used to cut the cross-section contours of a 3 D part and the grid hatchings of the part-exterior region on a sheet paper stack-wise. Using a laser beam as a cutter can be costly, and the thermal burning of a sheet paper along a laser scanning path can also cause an environment-polluting smoke. This paper presents a paper laminating RP system using a knife as the paper cutter instead of a laser beam. The knife holder is mounted through a radial bearing on the - positioning mechanism in such a way that the knife tip is eccentric to the bearing axis by a small distance (so-called offset). Therefore, the knife tip, which engages into the sheet paper during cutting, tends to follow the path of the -driven bearing axis by the error that depends on the path tangential and the eccentricity of the knife tip. A tractrix model is applied to describe the kinetic motion of the knife tip and a method is formulated to compensate for the tracing error of the eccentric knife tip by modifying the original cross-section contours of the part for each layer based on the tractrix equation. A study has also been performed regarding the effect of the knife tip geometry on the cutting notch of the sheet paper and on the roughness of the finished part.

关键词： rapid prototyping     laminated object manufacturing     knife-cutting     tracing error    

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Implicit Heaviside filter with high continuity based on suitably graded THB splines

《机械工程前沿（英文）》 2022年 第17卷 第1期   页码 14-14 doi: 10.1007/s11465-021-0670-2

摘要： The variable density topology optimization (TO) method has been applied to various engineering fields because it can effectively and efficiently generate the conceptual design for engineering structures. However, it suffers from the problem of low continuity resulting from the discreteness of both design variables and explicit Heaviside filter. In this paper, an implicit Heaviside filter with high continuity is introduced to generate black and white designs for TO where the design space is parameterized by suitably graded truncated hierarchical B-splines (THB). In this approach, the fixed analysis mesh of isogeometric analysis is decoupled from the design mesh, whose adaptivity is implemented by truncated hierarchical B-spline subjected to an admissible requirement. Through the intrinsic local support and high continuity of THB basis, an implicit adaptively adjusted Heaviside filter is obtained to remove the checkboard patterns and generate black and white designs. Threefold advantages are attained in the proposed filter: a) The connection between analysis mesh and adaptive design mesh is easily established compared with the traditional adaptive TO method using nodal density; b) the efficiency in updating design variables is remarkably improved than the traditional implicit sensitivity filter based on B-splines under successive global refinement; and c) the generated black and white designs are preliminarily compatible with current commercial computer aided design system. Several numerical examples are used to verify the effectiveness of the proposed implicit Heaviside filter in compliance and compliant mechanism as well as heat conduction TO problems.

关键词： topology optimization     truncated hierarchical B-spline     isogeometric analysis     black and white designs     Heaviside filter    

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旅客列车硬座车厢内气流模拟与浓度场分析

张登春,翁培奋

《中国工程科学》 2007年 第9卷 第11期   页码 80-86

摘要：

采用稳态不可压缩雷诺时均N-S方程、k-ε湍流模型，对旅客列车空调硬座车厢内气流场和浓度场进行了数值计算。采用立方体代表旅客，以人体呼出的CO2作为代表性污染物，研究了非空载下车厢内气流和浓度分布。计算结果表明：现有的送风方式除车厢两端外，车厢内沿长度方向气流分布比较均匀；人体散热和太阳辐射对车厢内流场温度场影响较大，非空载时车厢内流场分布与空载时有较大差别，太阳照射和人体产生的热气流使车厢内存在较大的温度梯度；车厢内过道区浓度较低，但座位区由于人员集中，人体呼吸区污染物积聚，浓度偏高，且车厢中部断面污染

关键词： 车厢     湍流模型     流场     浓度场     计算流体动力学    

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Anovel approach of noise statistics estimate using H∞ filter in target tracking

Xie WANG,Mei-qin LIU,Zhen FAN,Sen-lin ZHANG

《信息与电子工程前沿（英文）》 2016年 第17卷 第5期   页码 449-457 doi: 10.1631/FITEE.1500262

摘要： Noise statistics are essential for estimation performance. In practical situations, however, a priori information of noise statistics is often imperfect. Previous work on noise statistics identification in linear systems still requires initial prior knowledge of the noise. A novel approach is presented in this paper to solve this paradox. First, we apply the H∞ filter to obtain the system state estimates without the common assumptions about the noise in conventional adaptive filters. Then by applying state estimates obtained from the H∞ filter, better estimates of the noise mean and covariance can be achieved, which can improve the performance of estimation. The proposed approach makes the best use of the system knowledge without a priori information with modest computation cost, which makes it possible to be applied online. Finally, numerical examples are presented to show the efficiency of this approach.

关键词： Noise estimate     H∞     filter     Target tracking    

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Isolation and application of an ibuprofen-degrading bacterium to a biological aerated filter for the

Bingjie Xu, Gang Xue, Xing Yang

《环境科学与工程前沿（英文）》 2018年 第12卷 第5期 doi: 10.1007/s11783-018-1080-5

摘要：

• An ibuprofen-degrading strain, Serratia marcescens BL1, was isolated and identified.

• The effects of various factors on ibuprofen degradation by BL1 were evaluated.

• Strain BL1 was applied to a laboratory-scale biological aerated filter system.

• Strain BL1 was stable in both static tests and in the biological aerated filter system.

关键词： Ibuprofen     Biological aerated filter     Degrading bacterium     Serratia marcescens    

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标题 作者 时间 类型 操作

Study on enzymatic hydrolysis of steam exploded straw by using shaking ball

SUN Zhanwei, FU Xiaoguo, CHEN Hongzhang, WANG Yanhui, MA Runyu

期刊论文

The energy-free purification of trace thallium(I)-contaminated potable water using a high-selective filterpaper with multi-layered Prussian blue decoration

期刊论文

结合基于滤纸的DNA提取技术和RPA-LFD检测技术对有毒植物钩吻进行快速鉴别

郑夏生, 安文丽, 姚晖, 徐江, 陈士林

期刊论文

Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

期刊论文

Research progress on low dielectric constant modification of cellulose insulating paper for power transformers

期刊论文

Technical measures to achieve a cleaner production mode for recycled paper mills

Chao HE, Zhaolin GU, Shucheng YANG, Jidong LIANG, Weina DAI, Yanling HE

期刊论文

Investigation of electrochemical degradation and application of e-paper dyes in organic solvents

Luhai LI, Ming WANG, Yi FANG, Shunan QIAO

期刊论文

Easily-manufactured paper-based materials with high porosity for adsorption/separation applications in

期刊论文

论文演化图：学术文献多视角结构化检索

Dan-ping LIAO, Yun-tao QIAN

期刊论文

现代造纸机的节能与降耗

陈克复,杨旭

期刊论文

Error compensation for tool-tip trace during cutting of laminated paper for rapid prototyping

Yucheng DING, Changhe LI, Dichen LI, Guoxin YU

期刊论文

Implicit Heaviside filter with high continuity based on suitably graded THB splines

期刊论文

旅客列车硬座车厢内气流模拟与浓度场分析

张登春,翁培奋

期刊论文

Anovel approach of noise statistics estimate using H∞ filter in target tracking

Xie WANG,Mei-qin LIU,Zhen FAN,Sen-lin ZHANG

期刊论文

Isolation and application of an ibuprofen-degrading bacterium to a biological aerated filter for the

Bingjie Xu, Gang Xue, Xing Yang

期刊论文